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  8. N-Phenylbis-(trifluormethansulfonimid), 99 %, Thermo Scientific Chemicals

N-Phenylbis-(trifluormethansulfonimid), 99 %, Thermo Scientific Chemicals

Artikelnummer. 11383216
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Menge:
1 g
5 g
25 g
Unit Size:
1 Gramm
25 Gramm
5 Gramm
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Product Code. 11383216

Brand: Thermo Scientific Alfa Aesar L12531.14

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Description

CAS: 37595-74-7 | C8H5F6NO4S2 | 357.241 g/mol

N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation. Further, it is used in the enantioselective synthesis of beta-amino acids through the Mannich reaction. In addition to this, it is used in the preparation of sphingosine 1-phosphate-1 receptor agonists.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Anwendungen
N-Phenylbis(trifluormethanesulfonimid) fungiert als mildes Triflations-Reagenz sowie als transparentes starkes, elektronenabziehendes Dotiermittel des Typs p in Kohlenstoff-Nanoröhrchen. Es wird auch als Reaktant für die Herstellung amphoterischer alfa-Borylaldehyde eingesetzt. Es spielt eine wichtige Rolle bei der enantioselektiven Synthese des Kernring-Skeletts von Leucoceptroiden A-D und bei der steroselektiven Sulfoxidation. Weiter wird es bei der enantioselektiven Synthese von Beta-Aminosäuren durch die Mannich-Reaktion eingesetzt. Darüber hinaus wird es bei der Herstellung von Sphingosin-Phosphat 1-1-Rezeptor-Agonisten verwendet.

Löslichkeit
Löslich in Methanol. Schwer löslich in Chloroform und Ethylacetat.

Hinweise
Hygroskopisch. Kühl lagern. Feuchtigkeitsempfindlich. Nicht kompatibel mit starken Oxidationsmitteln.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 37595-74-7
Summenformel C8H5F6NO4S2
Molekulargewicht (g/mol) 357.241
MDL-Nummer MFCD00000404
InChI-Schlüssel DIOHEXPTUTVCNX-UHFFFAOYSA-N
Synonym n,n-bis trifluoromethylsulfonyl aniline, phenyl triflimide, n-phenyl-bis trifluoromethanesulfonimide, n-phenyltrifluoromethanesulfonimide, n,n-bis-trifluoromethanesulfonyl aniline, 1,1,1-trifluoro-n-phenyl-n-trifluoromethylsulfonyl methanesulfonamide, n-phenylbis trifluoromethanesulfonimide, n-phenylbis trifluoromethanesulphonimide, 1,1,1-trifluoro-n-phenyl-n-trifluoromethyl sulfonyl methanesulfonamide, n,n-bis trifluoromethanesulfonyl aniline
PubChem CID 142176
IUPAC-Name 1,1,1-Trifluor-N-phenyl-N-(trifluormethylsulfonyl)methansulfonamid
SMILES C1=CC=C(C=C1)N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

Specifications

Chemischer Name oder Material N-Phenylbis(trifluoromethanesulfonimide)
Schmelzpunkt 100°C to 102°C
Menge 25 g
Beilstein 1269141
Empfindlichkeit Moisture sensitive
Löslichkeitsinformationen Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.
Formelmasse 357.25
Reinheit (%) 99%

RUO – Research Use Only

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