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Hexaethylphosphortriamid, 97 %, Thermo Scientific Chemicals

Catalog Number 11494114
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Menge:
5 g
25 g
100 g
Dieser Artikel kann nicht zurückgegeben werden. Rückgaberichtlinie anzeigen
2283-11-6
MFCD00009041
Dieser Artikel kann nicht zurückgegeben werden. Rückgaberichtlinie anzeigen
2283-11-6
MFCD00009041

Hexaethyl phosphorous triamide is used in the Barton syntheses of hindered alkenes, involving desulfurization of small-ring heterocycles with elimination of nitrogen or carbon dioxide. It is also used as a reagent for selective vicinal dehalogenation of halogenated alkanes to give perhalogenated alkenes. The method has potential for the synthesis of highly fluorinated and mixed fluoro-halo alkenes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Hexaethyl phosphorous triamide is used in the Barton syntheses of hindered alkenes, involving desulfurization of small-ring heterocycles with elimination of nitrogen or carbon dioxide. It is also used as a reagent for selective vicinal dehalogenation of halogenated alkanes to give perhalogenated alkenes. The method has potential for the synthesis of highly fluorinated and mixed fluoro-halo alkenes.

Solubility
Insoluble in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents. It is sensitive to air. Store under dry inert gas.
TRUSTED_SUSTAINABILITY
Chemischer Name oder Material Hexaethyl phosphorous triamide
Dichte 0.903
Siedepunkt 245°C to 246°C
Flammpunkt 58°C (136°F)
Summenformel C8H4F3NO
Brechungsindex 1.4737
Menge 5 g
UN-Nummer UN1993
Beilstein 636187
Empfindlichkeit Air Sensitive
Synonym 2-trifluoromethyl phenyl isocyanate, 1-isocyanato-2-trifluoromethyl benzene, benzene, 1-isocyanato-2-trifluoromethyl, alpha,alpha,alpha-trifluoro-o-tolyl isocyanate, o-trifluoromethylphenylisocyanate, isocyanic acid, alpha,alpha,alpha-trifluoro-o-tolyl ester, o-trifluoromethyl phenyl isocyanate, 2-trifluoromethyl phenylisocyanate, 2-trifluoromethyl benzenisocyanate, isocyanic acid, .alpha.,.alpha.,.alpha.-trifluoro-o-tolyl ester
Löslichkeitsinformationen Insoluble in water.
InChI-Schlüssel GZWGTVZRRFPVAS-UHFFFAOYSA-N
SMILES C1=CC=C(C(=C1)C(F)(F)F)N=C=O
IUPAC-Name 1-isocyanato-2-(trifluoromethyl)benzene
Molekulargewicht (g/mol) 187.12
PubChem CID 16794
Formelmasse 247.37
Reinheit (%) 97%
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RUO – Research Use Only

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