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Allyltri-n-Butyltin, 97 %, Thermo Scientific Chemicals
Description
Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Allyltri-n-butyltin agiert als Allylierungsreagenz für Aldehyde, die durch chirale Lewis-Säuren und Ytterbium(III)-trifluormethansulfonat katalysiert werden. Wird auch zur Herstellung homoallylischer Alkohole mit Trichlor-1,3,5-triazin verwendet. Spielt eine wichtige Rolle bei der Tetrakis(triphenylphosphin)-palladium(0)-katalysierten Kupplungsreaktion mit Jodchinonen und Allylacetaten.
Löslichkeit
Nicht mit Wasser mischbar.
Hinweise
Luftempfindlich. Nicht kompatibel mit starken Oxidationsmitteln.
Specifications
Specifications
| Chemischer Name oder Material | Allyltri-n-butyltin |
| Dichte | 1.079 |
| Siedepunkt | 100°C to 102°C (0.5 mmHg) |
| Flammpunkt | 103°C (217°F) |
| Brechungsindex | 1.486 |
| Menge | 5 g |
| UN-Nummer | UN2788 |
| Beilstein | 3588340 |
| Empfindlichkeit | Air sensitive |
| Löslichkeitsinformationen | Immiscible with water. |
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RUO – Research Use Only
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