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Allyltri-n-Butyltin, 97 %, Thermo Scientific Chemicals

Artikelnummer. 11368955
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Product Code. 11368955 Supplier Thermo Scientific Alfa Aesar Supplier No. L14087.06
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CAS: 24850-33-7 | C15H32Sn | 331.13 g/mol

Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Anwendungen
Allyltri-n-butyltin agiert als Allylierungsreagenz für Aldehyde, die durch chirale Lewis-Säuren und Ytterbium(III)-trifluormethansulfonat katalysiert werden. Wird auch zur Herstellung homoallylischer Alkohole mit Trichlor-1,3,5-triazin verwendet. Spielt eine wichtige Rolle bei der Tetrakis(triphenylphosphin)-palladium(0)-katalysierten Kupplungsreaktion mit Jodchinonen und Allylacetaten.

Löslichkeit
Nicht mit Wasser mischbar.

Hinweise
Luftempfindlich. Nicht kompatibel mit starken Oxidationsmitteln.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 24850-33-7
Summenformel C15H32Sn
Molekulargewicht (g/mol) 331.13
MDL-Nummer MFCD00010346
InChI-Schlüssel YLGRTLMDMVAFNI-UHFFFAOYSA-N
Synonym allyltributyltin, allyltributylstannane, allyltri-n-butyltin, stannane, tributyl-2-propenyl, tributyl prop-2-en-1-yl stannane, allyl tributyl stannane, unii-aor8od4103, tributyl-2-propenylstannane, tri-n-butyl-2-propenylstannane, allyl tributyltin
PubChem CID 90628
SMILES CCCC[Sn](CCCC)(CCCC)CC=C

Specifications

Chemischer Name oder Material Allyltri-n-butyltin
Dichte 1.079
Siedepunkt 100°C to 102°C (0.5 mmHg)
Flammpunkt 103°C (217°F)
Brechungsindex 1.486
Menge 5 g
UN-Nummer UN2788
Beilstein 3588340
Empfindlichkeit Air sensitive
Löslichkeitsinformationen Immiscible with water.
IUPAC-Name Tributyl(prop-2-enyl)stannan
Formelmasse 331.12
Reinheit (%) 97%
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